- Author
- Rosasco, G. J. | May, A. D. | Hurst, W. S. | Petway, L. B. | Smyth, K. C.
- Title
- Broadening and Shifting of the Raman <b>Q</b> Branch of HD.
- Coporate
- National Institute of Standards and Technology, Gaithersburg, MD Toronto Univ., Canada Howard Univ., Washington, DC
- Journal
- Journal of Chemical Physics, Vol. 90, No. 4, 2115-2124, February 15, 1989
- Keywords
- energy transfer
- Abstract
- The line broadening and shifting of the vibrational Q branch in pure HD has been measured for transitions J=0 to 3 at room temperature over the density range 0.8 to 10.6 amagat. The shifting and broadening coefficients have been determined with an uncertainty of ±0.2x10-3cm-1/amagat, which now provides a discriminating test for various semiclassical and quantal theoretical calculations.