- Author
-
Miyoshi, A.
|
Widjaja, J.
|
Yamauchi, N.
|
Koshi, M.
|
Matsui, H.
- Title
- Direct Investigations on the Thermal Unimolecular Isomerization Reaction of 1-Pentyl Radicals.
- Coporate
- Tokyo Univ., Japan
Toyohashi University of Technology, Toyohashi, Japan
- Book or Conf
- Combustion Institute, Symposium (International) on Combustion, 29th. Proceedings. Volume 29. Part 1. July 21-25, 2002,
Combustion Institute, Pittsburgh, PA,
Sapporo, Japan,
Chen, J. H.; Colket, M. D., Editors,
1285-1293 p.,
2002
- Keywords
-
combustion
|
radicals
|
lasers
|
mass spectrometry
|
temperature
|
equations
|
pressure
- Identifiers
- Rice-Ramsperger-Kassel-Marcus (RRKM)/master equation; laser photolysis-photoionization mass spectrometry apparatus; ionization light sources used in the present study; ionization potentials of primary and secondary straight chain alkyl radicals; equilibrium between 1-Pentyl and 2-Pentyl radicals; molecular parameters used in the thermochemical and RRKM calculations; fall-off behavior and limiting high-pressure rate constant