- Author
-
Kamphus, M.
|
Braun-Unkhoff, M.
|
Hohse-Hoinghaus, K.
- Title
- Formation of Small PAHs in Laminar Premixed Low-Pressure Propene and Cyclopentene Flames: Experiment and Modeling.
- Coporate
- Universität Bielefeld, Universitätsstraße 25, D-33615 Bielefeld, Germany
Institut für Verbrennungstechnik, Deutsches Zentrum für Luft- und Raumfahrt e.V. (DLR), Pfaffenwaldring 38-40, D-70569 Stuttgart, Germany
- Journal
-
Combustion and Flame,
Vol. 152,
No. 1/2,
28-59,
January 2008
- Keywords
-
laminar flames
|
premixed flames
|
polycyclic aromatic hydrocarbons
|
low pressure
|
propene
|
cyclopentene
|
experiments
|
mass spectrometry
|
reaction kinetics
|
equations
|
concentration profiles
|
reaction mechanism
|
aromatic compounds
|
benzene
|
phenyl
|
sensitivity analysis
|
radicals
|
toluene
|
phenlacetylene
|
styrenes
- Identifiers
- in situ mass spectrometry; detailed chemical kinetic modeling; fuel-rich, nonsooting premixed flames of propene-oxygen-argon and cyclopentene-oxygen-argon; Laser Induced Fluorescence (LIF); molecular beam mass spectrometry (MBMS); electron impact ionization (EI); resonance-enhanced multiphoton ionization (REMPI); additional reactions included to describe the depletion of cyclopentene; maximum signal intensity in the cyclopentene flame vs maximum signal intensity in the propene flame; arrhenius expressions for reaction