- Author
-
Rosasco, G. J.
|
May, A. D.
|
Hurst, W. S.
|
Petway, L. B.
|
Smyth, K. C.
- Title
- Broadening and Shifting of the Raman <b>Q</b> Branch of HD.
- Coporate
- National Institute of Standards and Technology, Gaithersburg, MD
Toronto Univ., Canada
Howard Univ., Washington, DC
- Journal
-
Journal of Chemical Physics,
Vol. 90,
No. 4,
2115-2124,
February 15, 1989
- Keywords
-
energy transfer
- Abstract
- The line broadening and shifting of the vibrational Q branch in pure HD has been measured for transitions J=0 to 3 at room temperature over the density range 0.8 to 10.6 amagat. The shifting and broadening coefficients have been determined with an uncertainty of ±0.2x10-3cm-1/amagat, which now provides a discriminating test for various semiclassical and quantal theoretical calculations.