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Author
Babrauskas, V.
Title
Related Quantities. Part A. Heat of Combustion and Potential Heat.
Coporate
National Institute of Standards and Technology, Gaithersburg, MD
Report
Chapter 8,
Book or Conf
Heat Release in Fires, Elsevier Applied Science, NY, Babrauskas, V.; Grayson, S. J., Editors, 207-223 p., 1992
Keywords
heat release rate | fire protection engineering | heat of combustion | potential heat
Abstract
In a combustion reaction, the essential quantity is the heat of reaction. Since in typical combustion reactions we are dealing with constant-pressure, rather than constant-volume systems, it is most convenient to work with enthalpies, rather than energies. The enthalpy, H (kJ), is defined as: H = U + PV where U is the energy (kJ), P is the pressure (kPa), and V is the volume (m³). In thermodynamics and engineering calculations, specific enthalpy, h, is often used (and also specific energy, u). Molar units (kJ/mol) for these terms are typical in thermodynamics calculations, while in engineering computations it is often convenient to adopt mass (kJ/kg) units.