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Author
Fang, Z. | Xu, S. K. | Kozinski, J. A.
Title
Flameless Oxidation of Chlorinated Wastes in Supercritical Water Using Sodium Carbonate as the Oxidation Stimulant.
Coporate
McGill Univ., Montreal, Canada
Book or Conf
Combustion Institute, Symposium (International) on Combustion, 29th. Proceedings. Volume 29. Part 2. July 21-25, 2002, Combustion Institute, Pittsburgh, PA, Sapporo, Japan, Chen, J. H.; Colket, M. D., Editors, 2485-2492 p., 2002
Keywords
combustion | water | sodium carbonate | oxidation | FT-IR | polychlorinated biphenyls | cataltic effects
Identifiers
oxidation of decachlorobiphenyl (10-CB) in supercritical water was studied in the presence of Na2CO3, which was used as catalyst; in situ observations of the 10-CB oxidation process were carried out with a diamond anvil cell (DAC) coupled with optical and Fourier transform IR microscopes; phase behavior in a diamond anvil cell (DAC); investigations of phase change in the DAC; Super Critical Water (SCW); experimental conditions and results obtained in batch reactor at 450 deg C and 30 MPa