- Author
- Fang, Z. | Xu, S. K. | Kozinski, J. A.
- Title
- Flameless Oxidation of Chlorinated Wastes in Supercritical Water Using Sodium Carbonate as the Oxidation Stimulant.
- Coporate
- McGill Univ., Montreal, Canada
- Book or Conf
- Combustion Institute, Symposium (International) on Combustion, 29th. Proceedings. Volume 29. Part 2. July 21-25, 2002, Combustion Institute, Pittsburgh, PA, Sapporo, Japan, Chen, J. H.; Colket, M. D., Editors, 2485-2492 p., 2002
- Keywords
- combustion | water | sodium carbonate | oxidation | FT-IR | polychlorinated biphenyls | cataltic effects
- Identifiers
- oxidation of decachlorobiphenyl (10-CB) in supercritical water was studied in the presence of Na2CO3, which was used as catalyst; in situ observations of the 10-CB oxidation process were carried out with a diamond anvil cell (DAC) coupled with optical and Fourier transform IR microscopes; phase behavior in a diamond anvil cell (DAC); investigations of phase change in the DAC; Super Critical Water (SCW); experimental conditions and results obtained in batch reactor at 450 deg C and 30 MPa