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Author
Ferrante, M. J.
Title
High-Temperature Relative Enthalpies and Related Thermodynamic Properties of Na(2)Ti(6)O(13).
Coporate
Bureau of Mines, Pittsburgh, PA
Report
RI 9018
1986
10 p.
Keywords
thermal properties | high temperature
Abstract
Relative enthalpies of high-purity disodium hexatitanate (Na(2)Ti(60O913)) were measured at the Bureau of Mines to provide new thermodynamic data needed to advance the technology of materials. Measurements from 298.15 to 1,478 K were made by drop calorimetry with a copper block. Tabulated values are listed for the standard relative enthalpy, heat capacity, entropy, and Gibbs energy function between 298.15 and 1,500 K. Enthalpy data are also given in equation form and are combined with thermodynamic data from the literature to derive values of standard enthalpies of formation, Gibbs energies of formation, and logarithms of the equilibrium constants of formation. Similar calculations were made for the reaction of Na(2)O with TiO(2).