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Author
Matage, T. G.
Title
Thermal Cracking and Variable Properties Effects on Free Boundary Layer Diffusion Flames.
Coporate
California Univ., Berkeley
Sponsor
National Bureau of Standards, Gaithersburg, MD
Report
NBS GCR 88-542, March 1988, 45 p.
Distribution
Available from National Technical Information Service
Contract
NBS-GRANT-60NANB5D0552
Keywords
diffusion flames | cracking (fracturing) | boundary layers | flame spread | mathematical models | thermal cracking (chemistry)
Abstract
This paper presents an analytical model for a free convective boundary layer diffusion flame and compares results from this model to experiment. The analytical model will add two new features to the solution presented by Pagni in order to improve agreement with experimental data. It is proposed that the fuel undergoes endothermic decomposition before reaching the flame. The endorthermic decomposition of the fuel will be referred to as cracking. The effect of cracking on the free convective diffusion flame is explored by the use of modified Shvab Zeldovich variables which model both the flame reaction and the cracking reaction. the second addition to the solution given by Pagni is the use of a temperature dependent density-viscosity function which allows the ambient viscisity to be determined by ambient conditions. In order to match the location of the theoretical flame with the location of the experimental flame, previous studies have adjusted the ambient viscosity to non ambient values. By using the temperature dependent density-viscosity function, the analytical model accureatly predicts the location of the flame using the ambient value of viscosity.