- Author
-
Osmont, A.
|
Yahyaoui, M.
|
Catoire, L.
|
Gokalp, I.
|
Swihart, M. T.
- Title
- Thermochemistry of C-O, (CO)-O and (CO)-C Bond Breaking in Fatty Acid Methyl Esters.
- Coporate
- ICARE-CNRS and University of Orleans, 1C, avenue de la Recherche Scientifique, 45071 Orleans cedex 2, France
- Journal
-
Combustion and Flame,
Vol. 155,
No. 1/2,
334-342,
October 2008
- Keywords
-
methyl esters
|
thermochemistry
|
carbon
|
oxygen
|
carbon monoxide
|
fatty acids
|
combustion chemistry
|
validation
|
equations
- Identifiers
- gas-phase fatty acid methyl esters (FAMEs); names and structures of the five most important components in rapeseed oil methyl esters (RME) and soybean oil methyl esters (SME); derivation and validation of the computational method; atomic corrections used in the present study to compute the gas-phase standard enthalpy of formation at 298.15 K; comparison between experimental and computed gas-phase data obtained with the protocol proposed in this study; numbering of carbon atoms and of bonds in FAMEs illustrated in methyl palmitate and methyl palmitoleate