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Author
Baum, H. R. | Atreya, A.
Title
Model of Transport of Fuel Gases in a Charring Solid and Its Application to Opposed-Flow Flame Spread.
Coporate
National Institute of Standards and Technology, Gaithersburg, MD Michigan Univ., Ann Arbor
Report
Volume 31; Part 2,
Book or Conf
Combustion Institute, Symposium (International) on Combustion, 31st. Proceedings. Volume 31. Part 2. August 5-11, 2006, Combustion Institute, Pittsburgh, PA, Heidelberg, Germany, Barlow, R. S.; Sick, V.; Glarborg, P.; Yetter, R. A., Editors, 2633-2641 p., 2007
Keywords
combustion | fire research | flame spread | fuels | mathematical models | charring | solids | degradation | char | pressure differential | equations | mass transfer
Identifiers
fuel transport; charring solids; pressure generation; char matrix of a burning solid; gas transport model; transient thermal model; opposed flow flame spread
Abstract
This paper outlines the development of a mathematical model for the transport of gases through the char matrix of a burning solid. Two basic assumptions are made. First, the gases evolved by the degradation of the virgin material are transported by pressure differences through a network of narrow passageways created in the char by the conversion of material from the solid to the gas phase. This process is treated as flow through a porous medium, with the mass flux related to the pressure gradient by Darcy's law. Second, the gas temperature is the same as the local char temperature. This model is first used to study the time-dependent thermal degradation of a semi-infinite charring solid heated above the charring temperature. Then, the opposed flow flame spread treated by Atreya and Baum is revisited. It was found that the solution to the condensed phase flame spread problem is identical to the initial transient problem. Weak dependence of the solution on the accumulation parameter ß validates the assumption made in and completes the flame spread solution. Fuel mass flux follows the heat flux lines and is normal to the isobars. Calculations using representative values for wood show that the pressure generation at the char-virgin material interface is considerable and equal to 13.27 kPa. Finally, in view of the fact that the nonlinear pressure equation poses considerable numerical difficulties, this analytical solution may help in determining the stability and accuracy of the numerical scheme used for more complicated problems.