- Author
- Anikeev, V. | Tsang, W. | Manion, J. A.
- Title
- Density Effects in the Reaction of 2-Propanol in Supercritical Water.
- Coporate
- National Institute of Standards and Technology, Gaithersburg, MD
- Journal
- Combustion Science and Technology, Vol. 178, No. 1-3, 417-441, January/March 2006
- Sponsor
- Army Research Office
- Keywords
- water | density effects | propanol | experiments | heating | pumps | temperature measurements | propane | sampling | dehydration | temperature effects | acetone
- Identifiers
- supercritical water (SCW); reactions were carried out in a stirred batch reactor that features on-line sampling and direct injection of the sample into the SCW mixture; Autoclave Engineers (Autoclave Engineers, Erie, PA, 16506 USA) manufactured reactor; syringe pump; detailed breakdown of observed products for a representative experiment with 2-propanol; experimental pseudo-first-order rate constants for the main reactions in the 2-propanol system at 666K; mechanistic aspects