- Author
-
Anikeev, V.
|
Tsang, W.
|
Manion, J. A.
- Title
- Density Effects in the Reaction of 2-Propanol in Supercritical Water.
- Coporate
- National Institute of Standards and Technology, Gaithersburg, MD
- Journal
-
Combustion Science and Technology,
Vol. 178,
No. 1-3,
417-441,
January/March 2006
- Sponsor
- Army Research Office
- Keywords
-
water
|
density effects
|
propanol
|
experiments
|
heating
|
pumps
|
temperature measurements
|
propane
|
sampling
|
dehydration
|
temperature effects
|
acetone
- Identifiers
- supercritical water (SCW); reactions were carried out in a stirred batch reactor that features on-line sampling and direct injection of the sample into the SCW mixture; Autoclave Engineers (Autoclave Engineers, Erie, PA, 16506 USA) manufactured reactor; syringe pump; detailed breakdown of observed products for a representative experiment with 2-propanol; experimental pseudo-first-order rate constants for the main reactions in the 2-propanol system at 666K; mechanistic aspects