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Author
Liua, W. J. | Jeng, U. | Lin, T. L. | Laib, S. H. | Shih, M. C. | Tsao, C. S. | Wang, L. Y. | Chiang, L. Y. | Sung, L. P.
Title
Adsorption of Dodecahydroxylated-Fullerene Monolayers at the Air Water Interface.
Coporate
National Tsing Hua Univ., Taiwan National Chung-Hsin Univ., Taiwan Institute of Nuclear Energy Research, Lungtan, Taiwan National Taiwan Univ., Taipei National Institute of Standards and Technology, Gaithersburg, MD
Journal
Physica B: Condensed Matter, Vol. 283, No. 1/3, 49-52, 2000
Keywords
fullerene derivatives | monolayer | neutron reflection
Abstract
We study the adsorption behaviors of dodecahydroxylated-fullerene C60(OH)12 at the air-water interface. With the hydrophilicity imposed by the 12 hydroxy groups randomly bounded on the C60 cage, C60(OH)12 can dissolve in water slightly. Surface pressure-area isotherms, Brewster angle microscopy, and neutron reflection results for the aqueous solutions of C60(OH)12 provide consistent evidence of adsorbed C60(OH)12 monolayers at the air-water interface. A Langmuir-Blodgett film of C60(OH)12, prepared from the sample solution with the vertical dipping method, is examined using atomic force microscopy.