- Author
-
Korobeinichev, O. P.
|
Ilyin, S. B.
|
Bolshova, T. A.
|
Shvartsberg, V. M.
|
Chernov, A. A.
- Title
- Chemistry of the Destruction of Organophosphorus Compounds in Flames. Part 3. The Destruction of DMMP and TMP in a flame of Hydrogen and Oxygen.
- Coporate
- Siberian Branch Russian Academy of Sciences, Novosibirsk, Russia, 630090
- Journal
-
Combustion and Flame,
Vol. 123,
No. 4,
593-609,
June 2000
- Keywords
-
premixed flames
|
hydrogen
|
oxygen
|
toxic hazards
|
toxic materials
|
chemical warfare
|
chemical waste
|
hydrocarbons
|
concentration profiles
|
phosphorus
|
mole fraction
|
argon
- Identifiers
- dimethyl methyl phosphonate (DMMP); trimethyl phosphate (TMP); H2/O2/Ar (0.26/0.13/0.61 by volume) flame; mechanism for the destruction of DMMP; concentration profiles in the flame doped with DMMP; rate constants for H2/O2 and C1 hydrocarbon reactions; rate constants for reactions of the phosphorous oxides; rate constants for OPC intermediates; relative values of calibration coefficients (ki) for intermediates and other species normalized by argon; modeling of the structure of the flame doped with TMP