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Author
Struble, L. J. | Brown, P. W.
Title
Evaluation of Ettringite and Related Compounds for Use in Solar Energy Storage. Progress Report.
Coporate
National Bureau of Standards, Gaithersburg, MD
Sponsor
Department of Energy, Washington, DC
Report
NBSIR 84-2942
October 1984
Distribution
Available from National Technical Information Service
Keywords
solar energy; energy storage; synthesis (chemistry); performance evaluation; phase transformation; enthalpy; specific heat; temperature | phase transformations | solar energy
Identifiers
phase change materials; latent heat storage; ettringite
Abstract
This report describes an investigation of ettringite and related phases for potential application in solar energy storage. The specific objective is to evaluate the potential of ettringite dehydration and rehydration as a phase change for energy storage. Synthesis procedures have been developed, and a number of ettringite-type phases have been prepared. The heat capacity of each phase was approximately 0.3 calories per gram per degree Celcius. Studies of the dehydration of these phases at atmospheric pressure indicate that the material has good potential as a phase change material for solar energy storage. Dehydration occurred at temperatures in the range between approximately 30C and 55C, with changes in enthalpy ranging between 100 and 240 calories per gram sample. In addition, ettringite was found to have a reversible hydrothermal reaction at approximately 50C, with an enthalpy change of approximately 4 calories per gram sample. Future work during the remainder of this program will involve completing the work described in the present progress report.