- Author
-
Herbinet, O.
|
Pitz, W. J.
|
Westbrook, C. K.
- Title
- Detailed Chemical Kinetic Oxidation Mechanism for a Biodiesel Surrogate.
- Coporate
- Lawrence Livermore National Laboratory, Livermore, CA
- Journal
-
Combustion and Flame,
Vol. 154,
No. 3,
507-528,
August 2008
- Keywords
-
biodiesel
|
reaction kinetics
|
oxidation
|
low temperature
|
methyl decanote
|
experiments
|
soybeans
|
high temperature
|
equations
|
thermodynamic properties
|
ignition delay
|
low temperature
- Identifiers
- biodiesel fuels; average compositions (%) of soybean and rapeseed biodiesels; reactions of recombination involving CO and CC bonds in methyl decanoate; rate constants of the main reactions; inlet compositions of reacting mixtures used for methyl decanoate simulations in the jet-stirred reactor; inlet compositions of the reacting mixture used for the methyl decanoate-n-heptane surrogate simulations in the jet-stirred reactor; reactions leading to the formation of the radical OCHO; rates of the main reactions leading to the formation of CO2; calculated mass fractions (% of fuel C) for six consecutive cycles at CR = 6