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Author
Armstrong, G. T. | Jobe, T. L., Jr.
Title
Heating Values of Natural Gas and its Components. Technical Report.
Coporate
National Bureau of Standards, Gaithersburg, MD
Sponsor
Group International des Importateurs de Gaz Naturel Liquefie, Giignl
Report
NBSIR 82-2401, May 1982, 164 p.
Distribution
Available from National Technical Information Service
Keywords
liquefied natural gas | combustion | hydrocarbons
Abstract
This document gives the basic data needed, recommended procedures and illustrative calculations for computing heating values of natural gas mixtures from the composition of the mixtures and the properties of the components at commonly used reference conditions for gas measurement within the range 273.15 K to 298.15 K (0 deg. C to 25 deg. C). Symbols and terms used are defined, units of measurement are defined and conversion factors and phyical constant are given. Selected values for standard enthalpies of combustion and heat capacities of the pure hydrocarbon gases C1 to C6 gases are tabulated at the reference temperature 273.15 K (0 deg. C), 288.15 K (15 deg. C), 288.71 K (60 deg. F), and 298.15 K (25 deg. C) on a molar basis, and a volumetric basis. Both the dry gases and the ideal water-saturated gas are treated. The calucation of enthalpies of combustion of gas mixtures on a molar, mass, or volumetric basis is described. Second virial coefficient are resented as functions of temperature for the pure substances and for binary interactions with methane. Tables are given for molar volumes, enthalpic effects (H-H deg.) and the heating values of the dry real-gas hydrocarbons on a molar mass volumetric bases at to reference conditions, 288.15 K (15 deg. C), 101 325 Pa; and 288.71 (60 deg. F), 101 560 Pa (14.73 psia). An analysis is presented of the effects of errors in the data on calculated heating values.