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Author
Bentz, D. P. | Geiker, M. R. | Hansen, K. K.
Title
Shrinkage-Reducing Admixtures and Early Age Desiccation in Cement Pastes and Mortars.
Coporate
National Institute of Standards and Technology, Gaithersburg, MD Technical University of Denmark, Lyngby
Journal
Cement and Concrete Research, Vol. 31, No. 7, 1075-1085, July 2001
Keywords
cement paste | mortar | drying | humidity | shrinkage | surface tension
Abstract
Fundamental studies of the early age desiccation of cement-based materials with and without a shrinkage-reducing admixture (SRA) have been performed. Studies have been conducted under both sealed and drying conditions. Physical measurements include mass loss, surface tension, x-ray absorption to map the drying profile, internal relative humidity (RH), and autogenous deformation. Interestingly, although the SRA accelerates the drying of bulk solutions, in cement paste with a water-to-cement (w/c) ratio of 0.35, it actually reduces the measured drying rate. Based on the accompanying x-ray absorption measurements and a simple three-dimensional microstructure model, an explanation for this observation is proposed. In sealed systems, at equivalent hydration times, the SRA maintains a greter internal RH and reduces the induced autogenous deformation. Thus, these admixtures should be beneficial to low w/c ratio concretes undergoing self-desiccation, in addition to their normal usage to reduce drying shrinkage.