- Author
- Linteris, G. T. | Williams, F. A.
- Title
- Asymptotic and Numerical Analysis of a Premixed Laminar Nitrogen Dioxide-Hydrogen Flame.
- Coporate
- National Institute of Standards and Technology, Gaithersburg, MD University of California, San Diego, La Jolla
- Journal
- Combustion Science and Technology, Vol. 105, No. 4-6, 163-73, 1995
- Sponsor
- National Science Foundation, Washington, DC
- Contract
- CTS92-14888
- Keywords
- premixed flames | laminar flames | nitrogen dioxide | hydrogen | burning rate | flame structure
- Identifiers
- starting mechanism; asympotic analysis; one-step mechanism
- Abstract
- A kinetic mechanism of eighty-some reactions for flames in mixtures of hydrogen and nitrogen dioxide is systematically reduced to twenty-four-, eleven-, seven-, two-, and one-step mechanisms. The numerically predicted burning rates for the full mechanism are compared with the results using the reduced mechanisms, and the sources of inaccuracies are identified. The two reactions NO₂ + H -> NO + OH and H₂ + OH <- -> H₂O + H account for about 97% of the NO₂ and H₂ consumption and NO and H₂O production and are the principal reactions involving OH and H atoms. The reactions 2 OH <- -> H₂O + O and NO₂ + O -> NO + O₂ are important for OH and O, while the reactions NO₂ + M -> NO + O + M and NO₂ + H₂ -> HONO + H serve as important initiation reactions. The reactions O₂ + H <- -> OH + O, H₂ + O <- -> OH + H, and 2NO₂ -> 2NO + O₂ are significant but of lesser importance. In reducing the mechanism, the steady-state assumptions for the intermediates O, H, and OH are shown to be good; however, their use is limited because the H and OH balance relations are dominated by the same reactions. Despite these limitations, an asymptotic description of the flame structure using a one-step approximation to the kinetics is still able to predict the burning rate within a factor of three of the numerical result using the full mechanism.