- Author
-
Ploeger, J. M.
|
Bielenberg, P. A.
|
Dinaro-Blanchard, J. L.
|
Lachance, R. P.
|
Taylor, J. D.
|
Green, W. H.
|
Tester, J. W.
- Title
- Modeling Oxidation and Hydrolysis Reactions in Supercritical Water: Free Radical Elementary Reaction Networks and Their Applications.
- Coporate
- Massachusetts Institute of Technology, Cambridge
- Journal
-
Combustion Science and Technology,
Vol. 178,
No. 1-3,
363-398,
January/March 2006
- Keywords
-
water
|
oxidation
|
hydrolysis
|
kinetics
|
reaction mechanisms
|
free radicals
|
methane
|
benzene
|
validation
|
uncertainty
|
high pressure
|
hydrogen
- Identifiers
- supercritical water oxidation (SCWO); supercritical water (SCW); experimentally determined global rate laws for oxidation of selected model compounds in supercritical water; experimentally determined global rate laws for hydrolysis of selected model compounds in subcritical and supercritical water; reduced high-pressure hydrogen oxidation mechanism with reported uncertainty factors; sensitivity coefficients for MPA concentration at 800 K