FireDOC Search

Author
Sorensen, C. M. | Feke, G. D.
Title
Post-Flame Soot.
Coporate
Kansas State Univ., Manhattan
Sponsor
National Institute of Standards and Technology, Gaithersburg, MD
Contract
NIST-GRANT-70NANB4H1652
Book or Conf
National Institute of Standards and Technology (NIST) and Society of Fire Protection Engineers (SFPE). International Conference on Fire Research and Engineering (ICFRE). Proceedings. September 10-15, 1995, SFPE, Boston, MA, Orlando, FL, Lund, D. P.; Angell, E. A., Editors, 281-285 p., 1995
Keywords
fire research | smoke | soot | diffusion flames | equations | fractal dimensions | kinetics
Identifiers
transmission electron; optical microscopy; soot cluster radius of gyration; thermophoretic sampling; TEM analysis; Diffusion Limited Cluster Aggregation (DLCA)
Abstract
We have used an acetylene diffusion flame to create carbonaceous soot. The soot has been physically collected from all portions of the flame and the post-flame region. Inspection of the soot was performed with both transmission electron and optical microscopy. We measure soot cluster radius of gyration and show that these clusters retain their fractal morphology over nearly four orders of magnitude in size. The average fractal dimension is consistent with diffusion Limited Cluster Aggregation (DLCA). We also give evidence that the kinetics of growth when the soot clusters are on the order of lmm may be a gelation mechanism.