- Author
- Mathieu, O. | Frache, G. | Djebaili-Chaumeix, N. | Paillard, C. E. | Krier, G. | Muller, J. F. | Douce, F. | Manuelli, P.
- Title
- Laser Desorption-Ionization Time-of-Flight Mass Spectrometry for Analyses of Heavy Hydrocarbons Adsorbed on Soot Formed Behind Reflected Shock Waves.
- Coporate
- CNRS Orleans, 45071 Orleans Cedex 1, France Laboratoire de Spectrometrie de Masse et de Chimie Laser, Metz, France Total-Centre de Recherche de Solaize, 69360 Solaize, France Total France, 92907 Paris La Défense Cedex, France
- Report
- Volume 32; Part 1,
- Book or Conf
- Combustion Institute, Symposium (International) on Combustion, 32nd. Proceedings. Volume 32. Part 1. August 3-8, 2008, Combustion Institute, Pittsburgh, PA, Montreal, Canada, Dagaut, P.; Sick, V., Editors, 971-978 p., 2009
- Keywords
- combustion | hydrocarbons | soot | shock waves | lasers | mass spectroscopy | kinetics | shock tubes | soot formation | oxygen | temperature | polycyclic aromatic hydrocarbons
- Identifiers
- laser desorption/ionization time-of-flight mass spectrometry (LDIToFMS); effects of fuel structure (with 2-methyl-2-butene (2M2B)); fuel molecular composition (with thiophene, C4H4S); presence of oxygen (with toluene in pyrolysis; Transmission Electron Microscopy (TEM); shock-tube and soot collector; LDIToFMS set-up; soot formation kinetic parameters; experimental conditions obtained behind reflected shock waves; LDIToFMS results; effect of the structure of the hydrocarbon on adsorbed species on soot; effect of the oxygen on adsorbed species on soot; effect of a heteroatom in the organic fuel on adsorbed species on soot