- Author
-
Mathieu, O.
|
Frache, G.
|
Djebaili-Chaumeix, N.
|
Paillard, C. E.
|
Krier, G.
|
Muller, J. F.
|
Douce, F.
|
Manuelli, P.
- Title
- Laser Desorption-Ionization Time-of-Flight Mass Spectrometry for Analyses of Heavy Hydrocarbons Adsorbed on Soot Formed Behind Reflected Shock Waves.
- Coporate
- CNRS Orleans, 45071 Orleans Cedex 1, France
Laboratoire de Spectrometrie de Masse et de Chimie Laser, Metz, France
Total-Centre de Recherche de Solaize, 69360 Solaize, France
Total France, 92907 Paris La Défense Cedex, France
- Report
-
Volume 32; Part 1,
- Book or Conf
- Combustion Institute, Symposium (International) on Combustion, 32nd. Proceedings. Volume 32. Part 1. August 3-8, 2008,
Combustion Institute, Pittsburgh, PA,
Montreal, Canada,
Dagaut, P.; Sick, V., Editors,
971-978 p.,
2009
- Keywords
-
combustion
|
hydrocarbons
|
soot
|
shock waves
|
lasers
|
mass spectroscopy
|
kinetics
|
shock tubes
|
soot formation
|
oxygen
|
temperature
|
polycyclic aromatic hydrocarbons
- Identifiers
- laser desorption/ionization time-of-flight mass spectrometry (LDIToFMS); effects of fuel structure (with 2-methyl-2-butene (2M2B)); fuel molecular composition (with thiophene, C4H4S); presence of oxygen (with toluene in pyrolysis; Transmission Electron Microscopy (TEM); shock-tube and soot collector; LDIToFMS set-up; soot formation kinetic parameters; experimental conditions obtained behind reflected shock waves; LDIToFMS results; effect of the structure of the hydrocarbon on adsorbed species on soot; effect of the oxygen on adsorbed species on soot; effect of a heteroatom in the organic fuel on adsorbed species on soot