- Author
- Miyoshi, A. | Widjaja, J. | Yamauchi, N. | Koshi, M. | Matsui, H.
- Title
- Direct Investigations on the Thermal Unimolecular Isomerization Reaction of 1-Pentyl Radicals.
- Coporate
- Tokyo Univ., Japan Toyohashi University of Technology, Toyohashi, Japan
- Book or Conf
- Combustion Institute, Symposium (International) on Combustion, 29th. Proceedings. Volume 29. Part 1. July 21-25, 2002, Combustion Institute, Pittsburgh, PA, Sapporo, Japan, Chen, J. H.; Colket, M. D., Editors, 1285-1293 p., 2002
- Keywords
- combustion | radicals | lasers | mass spectrometry | temperature | equations | pressure
- Identifiers
- Rice-Ramsperger-Kassel-Marcus (RRKM)/master equation; laser photolysis-photoionization mass spectrometry apparatus; ionization light sources used in the present study; ionization potentials of primary and secondary straight chain alkyl radicals; equilibrium between 1-Pentyl and 2-Pentyl radicals; molecular parameters used in the thermochemical and RRKM calculations; fall-off behavior and limiting high-pressure rate constant