- Author
- Liaw, H. J. | Tang, C. L. | Lai, J. S.
- Title
- Model for Predicting the Flash Point of Ternary Flammable Solutions of Liquid.
- Coporate
- China Medical University, Taichung, Taiwan, Republic of China
- Journal
- Combustion and Flame, Vol. 138, No. 4, 308-319, September 2004
- Keywords
- flash point | flammable liquids | mathmatical models | equations
- Identifiers
- vapor-liquid equilibrium; ternary solutions; binary parameter; minimum flash point; some models for activity coefficients of multicomponent systems using only pure-component and binary parameters; antoine coefficients of the components; parameters of the Margules, Wilson, NRTL, and UNIQUAC equations for the ternary system containing methanol (1) + methyl acetate (2) + methyl acrylate (3); parameters of the Wilson, NRTL, and UNIQUAC equations for the ternary system containing methanol (1) + ethanol (2) + acetone (3); relative van der Waals volumes (r) and surface areas (q) for the pure components for the UNIQUAC model and the specific volume () for the pure components for the Wilson model; binary parameters of the Wilson, NRTL, and UNIQUAC equations for binary systems of methanol, methyl acetate, methyl acrylate, and binary systems of methanol, ethanol, and acetone; comparison of flash-point values adopted from the literature with experimentally derived data for the solution components used in this study; deviation between calculated and experimental flash point for binary and ternary solutions of methanol, methyl acetate, and methyl acrylate and the analogues of methanol, ethanol, and acetone