- Author
-
Buda, F.
|
Bounaceur, R.
|
Warth, V.
|
Glaude, P. A.
|
Fournet, R.
|
Battin-Leclerc, F.
- Title
- Progress Toward a Unified Detailed Kinetic Model for the Autoignition of Alkanes From C4 to C10 Between 600 and 1200 K.
- Coporate
- Département de Chimie Physique des Réactions, Nancy Cedex, France
- Journal
-
Combustion and Flame,
Vol. 142,
No. 1/2,
170-186,
July 2005
- Keywords
-
alkanes
|
autoignition
|
oxidation
|
kinetics
|
radicals
|
nitric oxide
|
ignition delay
- Identifiers
- Homogeneous Charge and Compression Ignition (HCCI); detailed kinetic model; summary of the experimental results published since 1993 concerning the autoignition of alkanes from C4 below 1200 K; kinetic parameters for the primary mechanism of the oxidation of alkanes not calculated using KINGAS; kinetic parameters for the additions of iso-octyl radicals to an oxygen molecule; parameters used for the calculation of the rate constants of internal isomerizations of alkylperoxy and hydroperoxy alkylperoxy free radicals; comparisons for the kinetic parameters for the formation of cyclic ethers; size of the generated mechanisms