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Author
Butler, K. M. | Baum, H. R. | Kashiwagi, T.
Title
Three-Dimensional Kinetic Model for the Swelling of Intumescent Materials.
Coporate
National Institute of Standards and Technology, Gaithersburg, MD
Report
NISTIR 5499, September 1994,
Book or Conf
National Institute of Standards and Technology. Annual Conference on Fire Research: BOOK OF ABSTRACTS. October 17-20, 1994, Gaithersburg, MD, 109-110 p., 1994
Keywords
fire research | intumescent coatings | kinetics | swelling | heat transfer | gasification | fire models
Abstract
An intumescent coating protects the underlying surface from fire by swelling into a thick insulating char. Design of intumescent materials has proceeded largely by systematic testing of a variety of formulations, since the mechanisms of physical, thermal and chemical behavior are not as yet well understood. Previous models of intumescent behavior have treated the system as a one-dimensional heat transfer problem through a coating consisting of a char layer and a layer of virgin material separated by a thin pyrolysis zone. In this work, a fully three-dimensional, time-dependent numerical model combining the dynamics of the swelling process, the heat transfer through the coating, and the chemistry of gasification is described.