- Author
- Kamphus, M. | Braun-Unkhoff, M. | Hohse-Hoinghaus, K.
- Title
- Formation of Small PAHs in Laminar Premixed Low-Pressure Propene and Cyclopentene Flames: Experiment and Modeling.
- Coporate
- Universität Bielefeld, Universitätsstraße 25, D-33615 Bielefeld, Germany Institut für Verbrennungstechnik, Deutsches Zentrum für Luft- und Raumfahrt e.V. (DLR), Pfaffenwaldring 38-40, D-70569 Stuttgart, Germany
- Journal
- Combustion and Flame, Vol. 152, No. 1/2, 28-59, January 2008
- Keywords
- laminar flames | premixed flames | polycyclic aromatic hydrocarbons | low pressure | propene | cyclopentene | experiments | mass spectrometry | reaction kinetics | equations | concentration profiles | reaction mechanism | aromatic compounds | benzene | phenyl | sensitivity analysis | radicals | toluene | phenlacetylene | styrenes
- Identifiers
- in situ mass spectrometry; detailed chemical kinetic modeling; fuel-rich, nonsooting premixed flames of propene-oxygen-argon and cyclopentene-oxygen-argon; Laser Induced Fluorescence (LIF); molecular beam mass spectrometry (MBMS); electron impact ionization (EI); resonance-enhanced multiphoton ionization (REMPI); additional reactions included to describe the depletion of cyclopentene; maximum signal intensity in the cyclopentene flame vs maximum signal intensity in the propene flame; arrhenius expressions for reaction